3-Chlorobenzaldehyde → HCID 68127574, compound

HRID 268009Notes

Reaction equation

HRID 268009 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][CH:9]=1)[CH:5]=O.[CH2:10]([O:12][C:13](=[O:22])[CH2:14][C:15]([C:17]([O:19][CH2:20][CH3:21])=[O:18])=O)[CH3:11].[CH2:23]([O:25][C:26](=[O:35])[C:27](=[NH:34])[CH2:28][C:29]([O:31][CH2:32][CH3:33])=[O:30])[CH3:24]>C(O)C>[CH2:20]([O:19][C:17]([C:15]1[NH:34][C:27]([C:26]([O:25][CH2:23][CH3:24])=[O:35])=[C:28]([C:29]([O:31][CH2:32][CH3:33])=[O:30])[CH:5]([C:4]2[CH:7]=[CH:8][CH:9]=[C:2]([Cl:1])[CH:3]=2)[C:14]=1[C:13]([O:12][CH2:10][CH3:11])=[O:22])=[O:18])[CH3:21]

Participants

5

Reactant 3

HCID 114773-ChlorobenzaldehydeHCID 66951Diethyl oxalacetateHCID 18977200Diethyl 2-iminobutanedioate

Product 1

HCID 68127574HCID 68127574, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

14.1 g of 3-chlorobenzaldehyde, 19 g of oxalacetic acid diethyl ester and 18.8 g of iminosuccinic acid diethyl ester in 60 ccs of ethanol are heated to the boil overnight and subsequently evaporated in vacuo. Yellow oil.

Workup

  1. customsubsequently evaporated in vacuo

Sources & evidence

ORD record
ord-0f7a6a44f4324658a20b3abefe413d92
Source dataset
uspto-grants-1976_03
Patent number
US03946027

Reaction notes

Loading…