Aluminium lithium hydride → HCID 14473012, compound

HRID 268114Notes

Reaction equation

HRID 268114 reaction equation
[CH2:1]=[C:2]1[CH2:7][CH2:6][CH2:5][C:4]([CH3:9])([CH3:8])[CH:3]1[CH:10]([OH:14])[C:11]#[C:12][CH3:13].[H-].[H-].[H-].[H-].[Li+].[Al+3]>>[CH2:1]=[C:2]1[CH2:7][CH2:6][CH2:5][C:4]([CH3:9])([CH3:8])[CH:3]1[CH:10]([OH:14])/[CH:11]=[CH:12]/[CH3:13]

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 21553504HCID 21553504, compound

Product 1

HCID 14473012HCID 14473012, compound

Procedure

Thus, e.g., if 2-methylene-6,6-dimethyl-1-[1-hydroxy-but-2-ynyl]-cyclohexane is reduced by means of LiAlH4, trans-2-methylene-6,6-dimethyl-1-[1-hydroxy-but-2-enyl]-cyclohexane is obtained.

Sources & evidence

ORD record
ord-117b33bf4fd040c2a6426cd2def1d0db
Source dataset
uspto-grants-1976_03
Patent number
US03946078

Reaction notes

Loading…