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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 268305Generated: October 31, 2026

Chlorotrimethylsilane → HCID 21454773, compound

https://huagongshe.com/reaction/268305

Reaction equation

Participants

RoleNameHCIDCharge
ReactantChlorotrimethylsilaneHCID 6397—
ReactantChlorotriethylsilaneHCID 13819—
Reactant2-OxazolidinoneHCID 73949—
ReactantResedineHCID 202193—
ProductHCID 21454773HCID 21454773—

Reaction Steps

This example is performed in a similar way to example 1, with the 2-oxazolidinone and the trimethylchlorosilane being replaced by 5-phenyl-2-oxazolidinone (57.11 g; 0.35 mol) and triethylchlorosilane (63.3 g; 0.42 mol) respectively. Once the solvent has been evaporated off, the result is crude 5-phenyl-3-triethylsilyl-2-oxazolidinone with a virtually quantitative yield. By methanolysis 5-phenyl-2-oxazolidinone is obtained. Calculated: 69.33%; found: 69.05%.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS03947465
Source datasetuspto-grants-1976_03
ORD IDord-c92492f2129945ea8310302a65966485
Source noteuspto-grants-1976_03