HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 268487Generated: October 29, 2026
Carbon Dioxide → 1-(1-Bromo-2,2,2-trifluoroethoxy)-1,1,2,2-tetrafluoroethane
https://huagongshe.com/reaction/268487
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Bromine | HCID 24408 | — |
| Reactant | (1H,1H-Perfluoroethyl)(2H-perfluoroethyl)ether | HCID 164596 | — |
| Product | 1-(1-Bromo-2,2,2-trifluoroethoxy)-1,1,2,2-tetrafluoroethane | HCID 71366137 | — |
Reaction Steps
CF3CH2OCF2CF2H (110 g.) was reacted with bromine (125 g.) by passing a mixture of the two diluted with a stream of nitrogen through a 12 inch × 1 inch glass tube heated to 475°C. The effluent product was condensed in a "Dry Ice" trap and purified by fractional distillation and preparative gas chromatography to give CF3CHBrOCF2CF2H., b.p. 80°C., nD25 1.3155. This product analyzed as follows:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US03947595 |
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| Source dataset | uspto-grants-1976_03 |
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| ORD ID | ord-2b87189c0a9c46669f12f8b3716d5616 |
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| Source note | uspto-grants-1976_03 |
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