Cellobionic acid → Lactobionic Acid
Reaction equation
[CH2:1]([OH:24])[C@H:2]1[O:7][C@@H:6]([O:8][C@@H:9]([C@H:14]([OH:20])[C@@H:15]([OH:19])[C:16]([OH:18])=[O:17])[C@H:10]([OH:13])[CH2:11][OH:12])[C@H:5]([OH:21])[C@@H:4]([OH:22])[C@@H:3]1[OH:23]>O>[CH2:1]([OH:24])[C@H:2]1[O:7][C@@H:6]([O:8][C@@H:9]([C@H:14]([OH:20])[C@@H:15]([OH:19])[C:16]([OH:18])=[O:17])[C@H:10]([OH:13])[CH2:11][OH:12])[C@H:5]([OH:21])[C@@H:4]([OH:22])[C@H:3]1[OH:23].[CH2:1]([OH:24])[C@H:2]1[O:7][C@@H:6]([O:8][C@@H:9]([C@H:14]([OH:20])[C@@H:15]([OH:19])[C:16]([OH:18])=[O:17])[C@H:10]([OH:13])[CH2:11][OH:12])[C@H:5]([OH:21])[C@@H:4]([OH:22])[C@@H:3]1[OH:23]Participants
Reactant 1
Product 2
Reagents, catalysts & solvents 1
Procedure
In one example, a gel matrix can be formed when aqueous solution comprising an oligosaccharide aldonic acid is evaporated at room temperature. The transparent gel thus obtained retains certain amount of water forming a clear gel matrix. The amount of water retention depends on individual oligosaccharide aldonic acid. For example, maltobionic acid 1 g in a beaker was dissolved in water 1 ml, and the solution thus obtained was left at room temperature. Fifty percent of the original water had been evaporated at the end of 24 hours, and 57% at the end of 48 hours, and 60% at the end of 72 hours, and no more or minimal evaporation of water could be detected after 72 hours. A clear gel film thus obtained contained 29% water complexed with maltobionic acid molecules. In the same manner, lactobionic acid formed a clear gel matrix with 14% water molecules and cellobionic acid formed a transparent gel with 7% water molecules. The formation of a gel matrix between an oligosaccharide aldonic acid and water has been found to have soothing, healing and slow-release effects in addition to other various beneficial effects to skin, mucous membrane, hair and nail.
Workup
- customis evaporated at room temperature
- customThe transparent gel thus obtained
- customthe solution thus obtained
- waitwas left at room temperature
- customFifty percent of the original water had been evaporated at the end of 24 hours, and 57% at the end of 48 hours, and 60% at the end of 72 hours
- customno more or minimal evaporation of water
- customA clear gel film thus obtained
Sources & evidence
- ORD record
- ord-f3ff93b5aa904b72b750e8aeb4b60b48
- Source dataset
- uspto-grants-2008_11
- Patent number
- US07452545B2
Reaction notes
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