Sodium Azide → HCID 178525423, compound

HRID 27135Notes

Reaction equation

HRID 27135 reaction equation
[C:1]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][NH:14][C:15](=[S:18])SC)([OH:3])=[O:2].[N-:19]=[N+:20]=[N-:21].[Na+]>>[C:1]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][N:14]1[C:15]([SH:18])=[N:21][N:20]=[N:19]1)([OH:3])=[O:2]

Participants

3

Reactant 2

HCID 33557Sodium AzideHCID 2057407811-{[(Methylsulfanyl)carbonothioyl]amino}undecanoic acid

Product 1

HCID 178525423HCID 178525423, compound

Procedure

Methyl 10-carboxydecyldithiocarbamate (28 g., 0.096 mol.) was reacted with 6.5 g. (0.1 mol.) of sodium azide according to the procedure described in Example 7. Acidification upon work-up gave 1-(10-carboxydecyl)tetrazole-5-thiol as a white precipitate, m.p. 95°-98°.

Sources & evidence

ORD record
ord-8f9a7f77cbff44b4b91123068a7ced40
Source dataset
uspto-grants-1980_09
Patent number
US04220644

Reaction notes

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