HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chlorotrimethylsilane → (1H-Inden-2-yl)(trimethyl)silane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | 1H-Indene, 2-bromo- | HCID 575586 | — |
| Reactant | Magnesium | HCID 5462224 | — |
| Product | (1H-Inden-2-yl)(trimethyl)silane | HCID 17819683 | — |
| Product | HCID 178419821 | HCID 178419821 | — |
Reaction Steps
Bromomagnesium indene was prepared from 10.0 g (51.3 mmol) of 2-bromoindene and 5 g of magnesium in a nitrogen stream. The reaction product was reacted with 6.5 ml of trimethylchlorosilane to obtain 7.14 g (37.9 mmol) of 2-trimethylsilylindene as a colorless oily product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07453005B2 |
| Source dataset | uspto-grants-2008_11 |
| ORD ID | ord-77ab20320a8d45b2b2661899ce53e347 |
| Source note | uspto-grants-2008_11 |