Methyl iodide → HCID 70504444, compound

HRID 27206Notes

Reaction equation

HRID 27206 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Cl:8])[C:3]=1[NH:9][C:10]([NH:12][C:13](=[O:19])[N:14]([CH2:17][CH3:18])[CH2:15][CH3:16])=[S:11].[I:20][CH3:21]>CO>[I-:20].[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Cl:8])[C:3]=1[NH+:9]=[C:10]([NH:12][C:13](=[O:19])[N:14]([CH2:17][CH3:18])[CH2:15][CH3:16])[S:11][CH3:21]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 133656121-(2,6-dichlorophenyl)-3-(N,N-diethylcarbamyl)thiourea

Product 1

HCID 70504444HCID 70504444, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

(0.1 mole) of 1-(2,6-dichlorophenyl)-3-(N,N-diethylcarbamyl) thiourea is combined with 200 ml of methanol and 14.1 g (0.1 mole) of iodomethane and refluxed for 4 hours. This is then evaporated to dryness and 100 ml of hexane is added. The mixture is filtered to obtain 1-(2,6-dichlorophenyl)-3-(N,N-diethylcarbamyl)-2-methylthiouronium iodide.

Workup

  1. temperaturerefluxed for 4 hours
  2. customThis is then evaporated to dryness and 100 ml of hexane
  3. additionis added
  4. filtrationThe mixture is filtered

Sources & evidence

ORD record
ord-3e17db455d774392973beb3e63b1ba5a
Source dataset
uspto-grants-1980_09
Patent number
US04220658

Reaction notes

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