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HRID27207

反应详情

EQUATION

反应方程式

HRID 27207 的结构方程式

REACTANTS

反应物

2
结构：CS(C)=O
HCID679

Dimethyl sulfoxide

C2H6OS

结构：C[C@]12CC[C@H]3[C@@H](CCC4=CC(=O)CC[C@@]43C)[C@@H]1CC[C@@H]2O
HCID6013

Testosterone

C19H28O2

PRODUCTS

生成物

1
结构：C[C@]12CC[C@H]3[C@@H]([C@H](O)CC4=CC(=O)CC[C@@]43C)[C@@H]1CC[C@@H]2O
HCID65541

未命名化合物

CONDITIONS

反应条件

温度
26.5 °C

PROCEDURE

实验过程

100 ml of the medium of Example 1 were inoculated with Mucor hiemalis FERM P-3800 and shaken at 26.5° C. for 22 hours. The culture was then treated with 50 mg of 17β-hydroxy-4-androsten-3one in 1 ml of dimethyl sulphoxide and incubated for 8 days. There were obtained from the culture filtrate 4.8 mg of 7α,17β-dihydroxy-4-androsten-3-one of melting point 191°-193° C.

WORKUP

后处理

  1. waitincubated for 8 days