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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 27392Generated: October 26, 2026

Propargylamine → HCID 178457545, compound

https://huagongshe.com/reaction/27392

Reaction equation

Participants

RoleNameHCIDCharge
ReactantPropargylamineHCID 239041—
ReactantMethyl 2-cyano-3,3-bis(methylsulfanyl)prop-2-enoateHCID 319957—
ReactantHCID 178433288HCID 178433288—
ReactantHCID 178500817HCID 178500817—
ProductHCID 178457545HCID 178457545—

Reaction Steps

When 1,1-bis(methylthio)-2-carbomethoxy-2-cyanoethylene [prepared according to the procedure described in Chem. Ber., 95, 2861 (1962)] is reacted with 2-[(4-methyl-1H-imidazol-5-yl)methylthio]ethylamine according to the procedure of Example 6, Step A, and the resultant 1-carbomethoxy-1-cyano-2-methylthio-2-{2-[(4-methyl-1H-imidazol-5-yl)-methylthio]ethylamino}ethylene treated with propargylamine by the procedure of Example 6, Step B, there is produced 1-carbomethoxy-1-cyano-2-(2-propynylamino)-2-{2-[(4-methyl-1H-imidazol-5-yl)methylthio]ethylamino}ethylene.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04221737
Source datasetuspto-grants-1980_09
ORD IDord-24a9e30174db480490dec92e911d3247
Source noteuspto-grants-1980_09