N-[1-(Methylsulfanyl)-2-nitroethenyl]prop-2-yn-1-amine → HCID 178457410, compound

HRID 27394Notes

Reaction equation

HRID 27394 reaction equation
CS[C:3]([NH:8][CH2:9][C:10]#[CH:11])=[CH:4][N+:5]([O-:7])=[O:6].[CH3:12][C:13]1[N:14]=[CH:15][NH:16][C:17]=1[CH2:18][S:19][CH2:20][CH2:21][NH2:22]>>[N+:5]([CH:4]=[C:3]([NH:8][C:9]#[C:10][CH3:11])[NH:22][CH2:21][CH2:20][S:19][CH2:18][C:17]1[NH:16][CH:15]=[N:14][C:13]=1[CH3:12])([O-:7])=[O:6]

Participants

3

Reactant 2

HCID 71401969N-[1-(Methylsulfanyl)-2-nitroethenyl]prop-2-yn-1-amineHCID 178433288HCID 178433288, compound

Product 1

HCID 178457410HCID 178457410, compound

Procedure

A solution of the product of Step A is treated with about an equimolar amount of 2-[(4-methyl-1H-imidazol-5-yl)-methylthio]ethylamine [prepared by the procedure described in U.S. Pat. No. 3,950,353] to produce, after workup and chromatography, the title product.

Workup

  1. customprepared by the procedure
  2. custom3,950,353] to produce

Sources & evidence

ORD record
ord-2ce7fd269f9e4446b6d8ca38bdeab20e
Source dataset
uspto-grants-1980_09
Patent number
US04221737

Reaction notes

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