5-Hydroxyfuran-2(5H)-one → HCID 86748445, compound

HRID 273941Notes

Reaction equation

HRID 273941 reaction equation
C(C1C(=O)OC(O)C=1)CCCCCCCCCCCC.OC1OC(=O)C=C1.C(CC[CH2:33][C:34]([O:36][CH:37]([C:50]1[CH:54]([OH:55])[O:53][C:52](=[O:56])[CH:51]=1)[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])=O)(O)=O.COCCOCOC(C1C(O)OC(=O)C=1)CCCCCCCCCCCC.C[S:85](NC(C1C(O)OC(=O)C=1)CCCCCCCCCCCC)(=O)=O.COC(NC(C1C(O)OC(=O)C=1)CCCCCCCCCCCC)=O.BrCCCC(OC(C1C(O)OC(=O)C=1)CCCCCCCCCCCC)=O>>[C:34]([O:36][CH:37]([C:50]1[CH:54]([OH:55])[O:53][C:52](=[O:56])[CH:51]=1)[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])(=[S:85])[CH3:33]

Participants

8

Reactant 7

HCID 210765-Hydroxyfuran-2(5H)-one4×HCID 15037083HCID 15037083, compound2×HCID 15728730HCID 15728730, compoundHCID 19433160HCID 19433160, compound2×HCID 19909502HCID 19909502, compound2×HCID 20094433HCID 20094433, compound2×HCID 20094434HCID 20094434, compound2×

Product 1

HCID 86748445HCID 86748445, compound

Procedure

4-[1-(glutarylamido)-tridecyl]-5-hydroxy-2(5H)-furanone (Compound 101); 4-[1-(N-methylcarbamoyl)-N-methyl)carbamoyl]tridecyl-5-hydroxy-2(5H)furanone (Compound 102); 4-[(1-phenylcarbamoyl)tridecyl]-5-hydroxy-2(5H)-furanone (Compound 103); 4-[1-ethoxycarbonyloxy)-tridecyl]-5-hydroxy-2(5H)-furanone (Compound 104); 4-[1-(4-carboxybutanoyloxy)tridecyl]-5-hydroxy-2(5H)-furanone (Compound 105); 4-[1-4-carbomethoxybutanoyloxy)tridecyl]-5-hydroxy-2(5H)-furanone (Compound 106); 4-[1-(2-methoxyethoxy)methoxytridecyl]-5-hydroxy-2(5H)-furanone; 4-[1-(methylsulfonamido)-tridecyl]-5-hydroxy-2(5H)-furanone (Compound 107); 4-(1-(methoxycarbonylamino)tridecyl]-5-hydroxy-2(5H)-furanone (Compound 108); 4-[1-(4-bromobutanoyloxy)tridecyl]-5-hydroxy-2(5H)-furanone (Compound 109), and 4-[1-PO(OCH3)CH3O-tridecyl]5-hydroxy-2(5H)-furanone (Compound 110).

Sources & evidence

ORD record
ord-e39c01dfda2740d897068b3e5b9da3bc
Source dataset
uspto-grants-1995_02
Patent number
US05387606

Reaction notes

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