3,5-Di-tert-butyl-4-hydroxybenzoyl chloride → HCID 21474580, compound

HRID 274040Notes

Reaction equation

HRID 274040 reaction equation
[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[C:12]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:13]=1[OH:14])[C:8](Cl)=[O:9])([CH3:4])([CH3:3])[CH3:2].[OH:19][CH2:20][C:21]1[CH:32]=[CH:31][C:24]([C:25]([O:27][CH2:28][CH:29]=[CH2:30])=[O:26])=[CH:23][CH:22]=1>>[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[C:12]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:13]=1[OH:14])[C:8]([O:19][CH2:20][C:21]1[CH:22]=[CH:23][C:24]([C:25]([O:27][CH2:28][CH:29]=[CH2:30])=[O:26])=[CH:31][CH:32]=1)=[O:9])([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 37871873,5-Di-tert-butyl-4-hydroxybenzoyl chlorideHCID 22392687Allyl 4-hydroxymethylbenzoate

Product 1

HCID 21474580HCID 21474580, compound

Procedure

In a manner similar to Example 1(d), by reaction of 7.7 g (28.6 mmol) of 3,5-di-tert-butyl-4-hydroxybenzoyl chloride with 5.5 g (28.6 mmol) of allyl 4-hydroxymethylbenzoate, 4.1 g (34%) of the expected allyl ester, melting point 100°-1° C., are obtained.

Workup

  1. customare obtained

Sources & evidence

ORD record
ord-79378db09ff0478b8be52326acb83763
Source dataset
uspto-grants-1995_02
Patent number
US05387594

Reaction notes

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