HCID 54515133, compound → HCID 20094757, compound

Participants

Reaction Steps

A mixture of 6-methoxy-2-(methoxycarbonylamino)indan-1-one ethylene dithioacetal (0.12 g), Raney nickel (suspension in water; 5 ml), and ethanol (12 ml) was refluxed for 0.5 hour. The mixture was filtered and the catalyst was washed with hot ethanol. The filtrate and washings were combined and concentrated in vacuo. Purification of the residue by column chromatography on silica gel (eluent; chloroform) gave 5-methoxy-N-methoxycarbonylindan-2-amine (0.08 g).

Provenance & Evidence