HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 54327415, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 2,3-Dichlorobenzaldehyde | HCID 35745 | — |
| Reactant | Lithium Chloride | HCID 433294 | — |
| Reactant | Water ethylacetate | HCID 22728543 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 54327415 | HCID 54327415 | — |
Reaction Steps
A mixture of 2,3-dichlorobenzaldehyde (17.5 g, 0.1 mol), triethyl phosphonoacetate (22.4 g, 0.12 mol), lithium chloride (5.1 g, 0.12 mol) and triethylamine (17 mL, 0.12 mol) in acetonitrile is stirred at room temperature for 1 hour and diluted with a water/ethyl acetate mixture. The organic phase is separated, washed with water dried over anhydrous Na2SO4 and concentrated in vacuo to give the title product as a yellow solid (42 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05389669 |
| Source dataset | uspto-grants-1995_02 |
| ORD ID | ord-43d407e56c724130980a985c037a8b20 |
| Source note | uspto-grants-1995_02 |