Thionyl Chloride → HCID 53883511, compound

HRID 274846Notes

Reaction equation

HRID 274846 reaction equation
[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH2:12][C:13]([OH:15])=O.S(Cl)([Cl:18])=O>C(Cl)(Cl)(Cl)Cl>[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH2:12][C:13]([Cl:18])=[O:15]

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 54184109HCID 54184109, compound

Product 1

HCID 53883511HCID 53883511, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

By the method of Example 1, Step E, 18.27 grams (0.073 mole) of 2,3-dichloro-5-nitrophenylacetic acid and 80 mL of thionyl chloride were reacted in 400 mL of carbon tetrachloride, yielding 20.90 grams of 2,3-dichloro-5-nitrophenylacetyl chloride. The NMR spectrum was consistent with the proposed structure.

Sources & evidence

ORD record
ord-ed0f53914a2f4847845b052a47652efb
Source dataset
uspto-grants-1995_02
Patent number
US05391541

Reaction notes

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