Benzoyl chloride → HCID 67808136, compound

HRID 275609Notes

Reaction equation

HRID 275609 reaction equation
[C:1](Cl)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[OH:10][CH2:11][C:12]([S:15]([CH2:18][CH:19]([CH2:30][C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1)[C:20]([O:22][CH2:23][C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)=[O:21])(=[O:17])=[O:16])([CH3:14])[CH3:13]>N1C=CC=CC=1>[C:1]([O:10][CH2:11][C:12]([S:15]([CH2:18][CH:19]([CH2:30][C:31]1[CH:32]=[CH:33][CH:34]=[CH:35][CH:36]=1)[C:20]([O:22][CH2:23][C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1)=[O:21])(=[O:17])=[O:16])([CH3:14])[CH3:13])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 7412Benzoyl chlorideHCID 54448487HCID 54448487, compound

Product 1

HCID 67808136HCID 67808136, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

In an analogous manner to that described in paragraph (d) above, by reacting benzoyl chloride with benzyl rac-α-[[(2-hydroxy-1,1-dimethylethyl)sulfonyl]methyl]hydrocinnamate in pyridine there was obtained benzyl rac-α-[[[2-(benzoyloxy)-l,1dimethylethyl]sulfonyl]methyl]hydrocinnamate as a colourless oil, MS: 403 (M-benzyl)+.

Sources & evidence

ORD record
ord-a69bba7c5d574e86ad53325e33f9d1c1
Source dataset
uspto-grants-1995_02
Patent number
US05393875

Reaction notes

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