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HRID275654

反应详情

EQUATION

反应方程式

HRID 275654 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])O
HCID944

Nitric Acid

HNO3

结构：Cn1c(C(F)(F)F)cc(=O)n(-c2cc(O)c(Cl)cc2F)c1=O
HCID11267757

未命名化合物

PRODUCTS

生成物

1
结构：Cn1c(C(F)(F)F)cc(=O)n(-c2c(F)cc(Cl)c(O)c2[N+](=O)[O-])c1=O
HCID18315086

未命名化合物

收率 35.5%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O=S(=O)(O)O
溶剂HCID1118

Sulfuric acid

H2O4S

PROCEDURE

实验过程

This compound was prepared in the manner of Step A of Example 1, using 3.8 grams (0.011 mole) of 1-methyl-6-trifluoromethyl-3-(4-chloro-2-fluoro-5-hydroxyphenyl)-2,4(1H,3H)-pyrimidinedione, 1.0 gram (0.011 mole) of 70% nitric acid, and 50 mL of sulfuric acid, yielding 1.5 grams of title compound. The NMR spectrum was consistent with the proposed structure.

WORKUP

后处理

  1. customThis compound was prepared in the manner of Step A of Example 1