HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetyl chloride → 1,1-Ethanediol, 1,1-diacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetyl chloride | HCID 6367 | — |
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 1,1-Ethanediol, 1,1-diacetate | HCID 222536 | — |
Reaction Steps
A 300-ml Fisher-Porter bottle was charged with 61.2 g (0.60 mol) of acetic anhydride, 0.3 g of a 5% palladium-on-carbon catalyst, and 0.8 g of acetyl chloride. The bottle was pressurized to 80-95 psig with hydrogen. After 4 hours at 90° C., a gas chromatographic analysis showed 18% conversion, with about equal amounts of ethylidene diacetate and acetic acid formed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04221918 |
| Source dataset | uspto-grants-1980_09 |
| ORD ID | ord-dca9bd852fc54eada48f212ce66fe2ed |
| Source note | uspto-grants-1980_09 |