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HRID277032

反应详情

EQUATION

反应方程式

HRID 277032 的结构方程式

REACTANTS

反应物

1
结构：NC(CS(=O)(=O)c1ccccc1)=NNC(=O)c1ccccc1
HCID86757848

未命名化合物

PRODUCTS

生成物

1
结构：O=S(=O)(Cc1n[nH]c(-c2ccccc2)n1)c1ccccc1
HCID178527398

未命名化合物

收率 75.6%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

93.1 g (0.29 mol) Benzenecarboxylic acid (1-amino-2-benzenesulfonyl-ethylidene)-hydrazide were heated at 200° C. for 30 minutes. The molten mass was then cooled, dissolved in 500 ml hot ethanol and stirred for 15 hous at room temperature. The precipitated crystals were filtered off and dried to yield 65.6 g (75%) 3-benzenesulfonylmethyl-5-phenyl-1H-[1,2,4]triazole with mp. 141-144° C. MS m/e (%): 299 (M+, 100).

WORKUP

后处理

  1. temperatureThe molten mass was then cooled
  2. filtrationThe precipitated crystals were filtered off
  3. customdried