HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Nitrophenyl chloroformate → HCID 22625966, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Nitrophenyl chloroformate | HCID 82129 | — |
| Reactant | Lithium diisopropylamide | HCID 2724682 | — |
| Reactant | HCID 22625979 | HCID 22625979 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 22625966 | HCID 22625966 | — |
Reaction Steps
The title compound was prepared by treating 10 (0.292 g, 0.767 mmol) with lithium diisopropylamide (2.0 M THF solution, 1.1 equivalents) in THF at −78° C. for 20 minutes followed by the rapid addition of 4-nitrophenyl chloroformate (1.5 equivalents) in THF. The 1H NMR was consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06358959B1 |
| Source dataset | uspto-grants-2002_03 |
| ORD ID | ord-e8ac49f494734f139286e12fbe1b54b8 |
| Source note | uspto-grants-2002_03 |