1-Bromohexane → HCID 11732181, compound

HRID 279422Notes

Reaction equation

HRID 279422 reaction equation
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

Participants

3

Reactant 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

Product 1

HCID 11732181HCID 11732181, compoundYield 91%

Procedure

2,7-Dichloro-9,9-di(1-hexyl)fluorene is prepared from 2,7-dichiorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C. HPLC analysis shows that the sample is 99 percent or greater pure and the spectral data confirms the title structure.

Workup

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C

Sources & evidence

ORD record
ord-42c0d486356c4c6baf54230a0da82d5f
Source dataset
uspto-grants-2002_03
Patent number
US06362310B1

Reaction notes

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