HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 9-beta-Hydroxyethyl-9,10-dihydro-9,10-methanoanthracene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Ethyl (9,10-methanoanthracen-9(10H)-yl)acetate | HCID 12507120 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | 9-beta-Hydroxyethyl-9,10-dihydro-9,10-methanoanthracene | HCID 13069085 | — |
Reaction Steps
A mixture of (9,10-dihydro-9,10-methano-9-anthryl)-acetic acid ethyl ester (125 mg) and lithium aluminum hydride (80 mg) in ether (6 ml) was stirred at room temperature for 1 hour. Excess lithium aluminum hydride was decomposed by addition of water. The reaction mixture was diluted with ethyl acetate, dried over anhydrous sodium sulfate and evaporated to dryness to give crystals of 9-β-hydroxyethyl-9,10-dihydro-9,10-methanoanthracene. M.P. 99°-100.5° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04224344 |
| Source dataset | uspto-grants-1980_09 |
| ORD ID | ord-a85fa2be2355424daa43edd90fad36b3 |
| Source note | uspto-grants-1980_09 |