HCID 13749502, compound → HCID 23322526, compound

HRID 279795Notes

Reaction equation

HRID 279795 reaction equation
[CH2:1]([O:8][C:9]([CH:11]([N:13]1[CH2:19][CH2:18][CH2:17][CH2:16][CH:15]([NH:20][CH:21]([C:30]([O:32]CC)=[O:31])[CH2:22][CH2:23][C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[C:14]1=[O:35])[CH3:12])=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.O=[C:37](CCC1C=CC=CC=1)C(OC(C)(C)C)=O>>[CH2:1]([O:8][C:9]([CH:11]([N:13]1[CH2:37][CH2:19][CH2:18][CH2:17][CH2:16][CH:15]([NH:20][CH:21]([C:30]([OH:32])=[O:31])[CH2:22][CH2:23][C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[C:14]1=[O:35])[CH3:12])=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 13749502HCID 13749502, compoundHCID 14187456HCID 14187456, compound

Product 1

HCID 23322526HCID 23322526, compound

Procedure

The diastereomers of this compound may be prepared from 3-amino-1-(1-benzyloxycarbonylethyl)perhydroazocin-2-one (Example 8) and t-butyl 2-oxo-4-phenylbutyrate following the procudure in Example 7.

Sources & evidence

ORD record
ord-ab8c904941704266808e5b82eb0576c5
Source dataset
uspto-grants-1986_05
Patent number
US04587050

Reaction notes

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