HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 70466764, compound → HCID 70466802, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 70466764 | HCID 70466764 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 70466802 | HCID 70466802 | 103.5% |
Reaction Steps
A solution of 6.8 g of 3-acetoxy-1α,2α-methylene-5α-androstan-17β-ol in 68 ml of dichloromethane is combined with 10.2 g of pyridinium chlorochromate and stirred for one hour at room temperature, then diluted with diethyl ether, washed with water, and dried. Evaporation yields 7.0 g of 3-acetoxy-1α,2α-methylene-5α-androstan-17-one.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04587235 |
| Source dataset | uspto-grants-1986_05 |
| ORD ID | ord-e67fb3ed9e1c435dbb3840429b65a395 |
| Source note | uspto-grants-1986_05 |