HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzene → HCID 178420620, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzene | HCID 241 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | Vanillin | HCID 1183 | — |
| Reactant | Piperidine | HCID 8082 | — |
| Reactant | HCID 20222317 | HCID 20222317 | — |
| Product | HCID 178420620 | HCID 178420620 | — |
Reaction Steps
A solution of 2.54 g of 4-hydroxy-3-methoxybenzaldehyde, 3.8 g of 2-carboxymalonanilic acid, and 4.29 g of piperidine in 17 ml of benzene is heated for 3 hours under reflux with removal of water of reaction. After completion of the reaction, the reaction mixture is cooled and the precipitated crystals are collected by filtration and dried to obtain 6.34 g of piperidinium N-(4-hydroxy-3-methoxycinnamoyl)anthranilate, mp. 188°-189° C. The compound structure is confirmed by elemental analysis, and by IR and NMR spectroscopy.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04587356 |
| Source dataset | uspto-grants-1986_05 |
| ORD ID | ord-0ec806ee364941769c7d9ffb4a9afac1 |
| Source note | uspto-grants-1986_05 |