Sodium Hydroxide → HCID 23671039, compound

HRID 280072Notes

Reaction equation

HRID 280072 reaction equation
[C:1]1([S:7][CH2:8][O:9][C:10]2[CH:18]=[CH:17][CH:16]=[CH:15][C:11]=2[C:12]([OH:14])=[O:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[Na+:20]>O>[C:1]1([S:7][CH2:8][O:9][C:10]2[CH:18]=[CH:17][CH:16]=[CH:15][C:11]=2[C:12]([O-:14])=[O:13])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1.[Na+:20]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 11777384Benzoic acid, 2-[(phenylthio)methoxy]-

Product 1

HCID 23671039HCID 23671039, compoundYield 98.6%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

126 g (0.48 mol) of 2-(phenylthio-methoxy)-benzoic acid were dissolved in 500 ml of water, with addition of 19.18 g (0.48 mol) of sodium hydroxide. The reaction mixture was stirred at room temperature for 30 minutes and then evaporated completely at 60° C. under reduced pressure. The colourless pulverulent product which remained was dried at 100° C. under reduced pressure for 16 hours. 133.5 g (98.6% of theory) of sodium 2-(phenylthio-methoxy)-benzoate of melting point 204°-207° C. were obtained in this manner.

Workup

  1. customevaporated completely at 60° C. under reduced pressure
  2. customThe colourless pulverulent product which remained was dried at 100° C. under reduced pressure for 16 hours

Sources & evidence

ORD record
ord-e40abef2cb724ae58ed9e6f671d98a41
Source dataset
uspto-grants-1986_05
Patent number
US04588433

Reaction notes

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