1-chloro-7-methoxy-4-nitro-10H-acridin-9-one → 1-Chloro-10-methyl-4-nitro-9(10H)-acridinone

HRID 280252Notes

Reaction equation

HRID 280252 reaction equation
ClC1C2C(=O)C3C(=CC=C(OC)C=3)NC=2C([N+]([O-])=O)=CC=1.[Cl:22][C:23]1[C:36]2[C:35](=[O:37])[C:34]3[C:29](=[CH:30][CH:31]=[C:32](OC)[CH:33]=3)[N:28]([CH3:40])[C:27]=2[C:26]([N+:41]([O-:43])=[O:42])=[CH:25][CH:24]=1>>[Cl:22][C:23]1[C:36]2[C:35](=[O:37])[C:34]3[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=3)[N:28]([CH3:40])[C:27]=2[C:26]([N+:41]([O-:43])=[O:42])=[CH:25][CH:24]=1

Participants

3

Reactant 2

HCID 4382311-chloro-7-methoxy-4-nitro-10H-acridin-9-oneHCID 135883401-chloro-7-methoxy 10-methyl-4-nitro-9(10H)-acridinone

Product 1

HCID 135883211-Chloro-10-methyl-4-nitro-9(10H)-acridinone

Procedure

In the same manner, 7.62 g (0.025 mol) of 1-chloro-7-methoxy-4-nitro-9(10H)-acridinone was converted to 5.05 g (63%) of 1-chloro-7-methoxy-10-methyl-4-nitro-9(10H)-acridinone, mp 235-240 degrees after recrystallization from toluene.

Workup

  1. customafter recrystallization from toluene

Sources & evidence

ORD record
ord-b7b2c9f8b89640b6aad52a50d7291151
Source dataset
uspto-grants-1986_05
Patent number
US04588730

Reaction notes

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