Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
N,N-Dimethylaniline → 1,6-dichloro-7-methoxy-4-nitro-9(10H)-acridinone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | N,N-Dimethylaniline | HCID 949 | — |
| 반응물 | Phosphorus oxychloride | HCID 24813 | — |
| 반응물 | 6-Chloro-2-[(3-chloro-4-methoxyphenyl)amino]-3-nitrobenzoic acid | HCID 13588347 | — |
| 용매 | 1,2-Dichloroethane | HCID 11 | — |
| 생성물 | 1,6-dichloro-7-methoxy-4-nitro-9(10H)-acridinone | HCID 13588331 | — |
반응 단계
A mixture of 17 g of 6-chloro-2-[(3-chloro-4-methoxyphenyl)amino]-3-nitrobenzoic acid, 35 ml of phosphorus oxychloride, 1 ml of N,N-dimethylaniline and 150 ml 1,2-dichloroethane was heated under reflux for 45 minutes. The resulting solid was collected by filtration from the hot reaction mixture and was washed with chloroform to provide 1,6-dichloro-7-methoxy-4-nitro-9(10H)-acridinone, mp 284°-285° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04588730 |
| 출처 데이터셋 | uspto-grants-1986_05 |
| ORD ID | ord-6deb89f2f8274ae29ed35081d8032961 |
| 출처 메모 | uspto-grants-1986_05 |