Ethanol → HCID 23320751, compound

HRID 280552Notes

Reaction equation

HRID 280552 reaction equation
[CH2:1]([OH:3])[CH3:2].Cl[C:5]1[C:9]2[C:10]([N+:14]([O-:16])=[O:15])=[CH:11][CH:12]=[CH:13][C:8]=2[S:7](=[O:18])(=[O:17])[N:6]=1>ClCCl>[CH2:1]([O:3][C:5]1[C:9]2[C:10]([N+:14]([O-:16])=[O:15])=[CH:11][CH:12]=[CH:13][C:8]=2[S:7](=[O:17])(=[O:18])[N:6]=1)[CH3:2]

Participants

4

Reactant 2

HCID 702EthanolHCID 23320748HCID 23320748, compound

Product 1

HCID 23320751HCID 23320751, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Ethanol (100 ml) was added to a solution of 3-chloro-4-nitro-benzoisothiazole-1,1-dioxide (0.86 g) in dichloromethane (110 ml). The resulting solution was allowed to stand overnight at room temperature. Removal of the solvent in vacuo gave an amorphous brown solid, which was triturated under ether (100 ml) to give the title compound as a white solid (0.82 g), mpt 190°-191° C.

Workup

  1. customRemoval of the solvent in vacuo
  2. customgave an amorphous brown solid, which
  3. customwas triturated under ether (100 ml)

Sources & evidence

ORD record
ord-1d7fbeee813a499892bfbfd33c9e0697
Source dataset
uspto-grants-1986_05
Patent number
US04590192

Reaction notes

Loading…