HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dicyclopentadiene → Cydecanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dicyclopentadiene | HCID 6492 | — |
| Reactant | Deca-8-yl acrylate | HCID 17853765 | — |
| Reactant | Deca-8-yl methacrylate | HCID 22140531 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Solvent | Water | HCID 962 | — |
| Product | Cydecanol | HCID 94137 | — |
Reaction Steps
The compound of the formula: ##STR3## wherein Rl is hydrogen or a methyl group, that is, tricyclo-[5.2.1.02,6 ]deca-8-yl methacrylate or tricyclo[5.2.1.02,6 ]-deca-8-yl acrylate, can be prepared by a conventional process for synthesizing a methacrylic or acrylic acid ester. For example, the compound of the formula (I) can be prepared by adding H2O to dicyclopentadiene to give dicyclopentenyl alcohol, which is changed to tricyclo-[5.2.1.02,6 ]deca-8-ol by catalytic hydrogenation reaction, followed by ester exchange reaction with methyl methacrylate or methyl acrylate, or condensation reaction with methacrylic acid, acrylic acid, methacrylic acid chloride or acrylic acid chloride.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04591626 |
| Source dataset | uspto-grants-1986_05 |
| ORD ID | ord-3c3aeb1e64974891ac6318f6cb636213 |
| Source note | uspto-grants-1986_05 |