4-(Bromomethyl)-1-fluoro-2-phenoxybenzene → HCID 23338854, compound
Reaction equation
[C:1]1([S:7][CH:8]2[CH:10]([C:11]([OH:13])=[O:12])[C:9]2([CH3:15])[CH3:14])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[F:16][C:17]1[CH:24]=[CH:23][C:20]([CH2:21]Br)=[CH:19][C:18]=1[O:25][C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1>>[C:1]1([S:7][CH:8]2[CH:10]([C:11]([O:13][CH2:21][C:20]3[CH:23]=[CH:24][C:17]([F:16])=[C:18]([O:25][C:26]4[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=4)[CH:19]=3)=[O:12])[C:9]2([CH3:15])[CH3:14])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1Participants
3
Procedure
Using the method of Example 3, 3-phenylthio-2,2-dimethylcyclopropanecarboxylic acid is reacted with 4-fluoro-3-phenoxybenzyl bromide to yield 4-fluoro-3-phenoxybenzyl 3-phenylthio-2,2-dimethylcyclopropanecarboxylate.
Sources & evidence
- ORD record
- ord-da2fc70519db4a2f9e2e104b95db3317
- Source dataset
- uspto-grants-1980_09
- Patent number
- US04225533
Reaction notes
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