HRID28103

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID12874224

(4-Fluoro-3-phenoxyphenyl)methanol

C13H11FO2

HCID15681057

(2-Fluoro-5-phenoxyphenyl)methanol

C13H11FO2

HCID54542542

未命名化合物

PRODUCTS

生成物

结构：CC(C)COC1C(C(=O)OCc2ccc(F)c(Oc3ccccc3)c2)C1(C)C

HCID23338880

未命名化合物

结构：CC(C)COC1C(C(=O)OCc2cc(Oc3ccccc3)ccc2F)C1(C)C

HCID54242770

未命名化合物

PROCEDURE

实验过程

Using the procedure of Example 14, each of 4-fluoro-3-phenoxybenzyl alcohol and 2-fluoro-5-phenoxybenzyl alcohol is reacted with 3-(i-butoxy)-2,2-dimethylcyclopropanecarboxylic acid to yield 4-fluoro-3-phenoxybenzyl 3-(i-butoxy)-2,2-dimethylcyclopropanecarboxylate and 2-fluoro-5-phenoxybenzyl 3-(i-butoxy)-2,2-dimethylcyclopropanecarboxylate.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-3728e506000b471c9235231062fcac3b
来源数据集: uspto-grants-1980_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04225533
来源说明: uspto-grants-1980_09

反应 SMILES

[F:1][C:2]1[CH:9]=[CH:8][C:5]([CH2:6][OH:7])=[CH:4][C:3]=1[O:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[F:17][C:18]1[CH:25]=[CH:24][C:23]([O:26][C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)=[CH:22][C:19]=1[CH2:20][OH:21].[CH2:33]([O:37][CH:38]1[CH:40]([C:41](O)=[O:42])[C:39]1([CH3:45])[CH3:44])[CH:34]([CH3:36])[CH3:35]>>[CH2:33]([O:37][CH:38]1[CH:40]([C:41]([O:7][CH2:6][C:5]2[CH:8]=[CH:9][C:2]([F:1])=[C:3]([O:10][C:11]3[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=3)[CH:4]=2)=[O:42])[C:39]1([CH3:45])[CH3:44])[CH:34]([CH3:36])[CH3:35].[CH2:33]([O:37][CH:38]1[CH:40]([C:41]([O:21][CH2:20][C:19]2[CH:22]=[C:23]([O:26][C:27]3[CH:28]=[CH:29][CH:30]=[CH:31][CH:32]=3)[CH:24]=[CH:25][C:18]=2[F:17])=[O:42])[C:39]1([CH3:45])[CH3:44])[CH:34]([CH3:36])[CH3:35]