3-(5-Chlorobenzotriazol-2-yl)-5-tert-butyl-4-hydroxyhydrocinnamic acid → 1-(2-Nitro-4-chlorophenoxy)-2,2,6,6-tetramethyl-piperidin-4-yl 3-(5-Chlorobenzotriazol-2-yl)-5-tert-butyl-4-hydroxyhydrocinnamate
Reaction equation
[Cl:1][C:2]1[CH:26]=[CH:25][C:5]2=[N:6][N:7]([C:9]3[CH:10]=[C:11]([CH:17]=[C:18]([C:21]([CH3:24])([CH3:23])[CH3:22])[C:19]=3[OH:20])[CH2:12][CH2:13][C:14]([OH:16])=[O:15])[N:8]=[C:4]2[CH:3]=1.[N+:27]([C:30]1[CH:47]=[C:46]([Cl:48])[CH:45]=[CH:44][C:31]=1[O:32][N:33]1[C:38]([CH3:40])([CH3:39])[CH2:37][CH:36](O)[CH2:35][C:34]1([CH3:43])[CH3:42])([O-:29])=[O:28]>>[Cl:1][C:2]1[CH:26]=[CH:25][C:5]2=[N:6][N:7]([C:9]3[CH:10]=[C:11]([CH:17]=[C:18]([C:21]([CH3:22])([CH3:23])[CH3:24])[C:19]=3[OH:20])[CH2:12][CH2:13][C:14]([O:16][CH:36]3[CH2:35][C:34]([CH3:43])([CH3:42])[N:33]([O:32][C:31]4[CH:44]=[CH:45][C:46]([Cl:48])=[CH:47][C:30]=4[N+:27]([O-:29])=[O:28])[C:38]([CH3:40])([CH3:39])[CH2:37]3)=[O:15])[N:8]=[C:4]2[CH:3]=1Participants
3
Reactant 2
Product 1
Procedure
The title compound is prepared according to the procedure of Example 3 using 3-(5-chlorobenzotriazol-2-yl)-5-tert-butyl-4-hydroxyhydrocinnamic acid and 1-(2-nitro-4-chloro-phenoxy)-2,2,6,6-tetramethyl-4-hydroxypiperidine.
Sources & evidence
- ORD record
- ord-4ace43001ab84d07a52098d7d78fe4a3
- Source dataset
- uspto-grants-2008_09
- Patent number
- US07419513B2
Reaction notes
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