Methanol → Dimethyl 4'-cyanobiphenyl-3,5-dicarboxylate

HRID 313503Notes

Reaction equation

HRID 313503 reaction equation
[C:16](#[N:17])[c:18]1[cH:19][cH:20][c:21]([B:24]([OH:25])[OH:26])[cH:22][cH:23]1.[C:27](=[O:28])([O-:29])[O-:30].[CH3:33][OH:34].[I:1][c:2]1[cH:3][c:4]([C:12](=[O:13])[O:14][CH3:15])[cH:5][c:6]([C:7](=[O:8])[O:9][CH3:10])[cH:11]1.[Na+:31].[Na+:32]>>[c:2]1(-[c:21]2[cH:20][cH:19][c:18]([C:16]#[N:17])[cH:23][cH:22]2)[cH:3][c:4]([C:12](=[O:13])[O:14][CH3:15])[cH:5][c:6]([C:7](=[O:8])[O:9][CH3:10])[cH:11]1

Participants

6

Reactant 5

HCID 887MethanolHCID 923Sodium ion2×HCID 19660Carbonate IonHCID 27343264-Cyanophenylboronic acidHCID 2758568Dimethyl 5-iodoisophthalate

Product 1

HCID 57513453Dimethyl 4'-cyanobiphenyl-3,5-dicarboxylate

Sources & evidence

ORD record
ord-e613f3daa4a54ee4a8cb0e0dd920c8f9
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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