1,4-Dioxane → 1-(2-Methyl-4-nitrophenyl)-3-vinylpyridin-2(1H)-one

HRID 316712Notes

Reaction equation

HRID 316712 reaction equation
[Br:1][c:2]1[c:3](=[O:18])[n:4](-[c:8]2[c:9]([CH3:17])[cH:10][c:11]([N+:14](=[O:15])[O-:16])[cH:12][cH:13]2)[cH:5][cH:6][cH:7]1.[CH2:19]([CH2:20][CH2:32][CH3:33])[C:21]([Sn:22])=[C:23]([CH2:24][CH2:25][CH2:26][CH3:27])[CH2:28][CH2:29][CH2:30][CH3:31].[O:34]1[CH2:35][CH2:36][O:37][CH2:38][CH2:39]1.[cH:40]1[cH:41][cH:42][c:43]([P:44]([Pd:45]([P:46]([c:47]2[cH:48][cH:49][cH:50][cH:51][cH:52]2)([c:53]2[cH:54][cH:55][cH:56][cH:57][cH:58]2)[c:59]2[cH:60][cH:61][cH:62][cH:63][cH:64]2)([P:65]([c:66]2[cH:67][cH:68][cH:69][cH:70][cH:71]2)([c:72]2[cH:73][cH:74][cH:75][cH:76][cH:77]2)[c:78]2[cH:79][cH:80][cH:81][cH:82][cH:83]2)[P:84]([c:85]2[cH:86][cH:87][cH:88][cH:89][cH:90]2)([c:91]2[cH:92][cH:93][cH:94][cH:95][cH:96]2)[c:97]2[cH:98][cH:99][cH:100][cH:101][cH:102]2)([c:103]2[cH:104][cH:105][cH:106][cH:107][cH:108]2)[c:109]2[cH:110][cH:111][cH:112][cH:113][cH:114]2)[cH:115][cH:116]1>>[c:2]1([CH:19]=[CH2:20])[c:3](=[O:18])[n:4](-[c:8]2[c:9]([CH3:17])[cH:10][c:11]([N+:14](=[O:15])[O-:16])[cH:12][cH:13]2)[cH:5][cH:6][cH:7]1

Participants

5

Reactant 4

HCID 312751,4-DioxaneHCID 53438229Tri(butyl)vinyltinHCID 594101573-Bromo-1-(2-methyl-4-nitrophenyl)pyridin-2(1H)-oneHCID 178420554HCID 178420554, compound

Product 1

HCID 594101981-(2-Methyl-4-nitrophenyl)-3-vinylpyridin-2(1H)-one

Sources & evidence

ORD record
ord-8528b19abcc04e0a8cf2ffb045e32941
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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