HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | 1,2-Diethylbenzene | HCID 8657 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide | HCID 59793205 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine | HCID 59793193 | 85.5% |
Reaction Steps
Charged were N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide 82.0 g, a 50% potassium hydroxide aqueous solution 39 g and diethylbenzene 100 ml, and the mixture was heated and refluxed for 3 days. After finishing the reaction, the mixture was left cooling down, and water 100 ml and hexane 500 ml were added thereto. The brown solid matter deposited was filtered off and dried under reduced pressure to obtain 67 g of N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07425654B2 |
| Source dataset | uspto-grants-2008_09 |
| ORD ID | ord-86bb213d299e42d6ac8e1d5218b776b3 |
| Source note | uspto-grants-2008_09 |