Alumina → HCID 178520565, compound

HRID 322607Notes

Reaction equation

HRID 322607 reaction equation
[O-2].[Al+3].[O-2].[O-2].[Al+3].C([O:8][C:9](=O)[CH2:10][CH2:11][CH2:12][CH2:13][C-:14]1[CH:18]=[CH:17][CH:16]=[CH:15]1)C.[CH-:20]1[CH:24]=[CH:23][CH:22]=[CH:21]1.[Fe+2:25]>C(Cl)Cl>[C-:14]1([CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][OH:8])[CH:18]=[CH:17][CH:16]=[CH:15]1.[CH-:20]1[CH:24]=[CH:23][CH:22]=[CH:21]1.[Fe+2:25]

Participants

4

Reactant 2

HCID 9989226Alumina2×HCID 178471292HCID 178471292, compound

Product 1

HCID 178520565HCID 178520565, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

Yield: 378 mg (89% of the theoretical) TLC: Rf (aluminum oxide, CH2Cl2)=0.2 Column chromatography: aluminum oxide, neutr. (act. III), CH2Cl2

Sources & evidence

ORD record
ord-e7704ad5b6424d6fa7f7110fcbae96b8
Source dataset
uspto-grants-2001_04
Patent number
US06211356B1

Reaction notes

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