HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-Decene → 1-Hexene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-Decene | HCID 23916 | — |
| Reactant | 9-Decen-1-ol | HCID 25612 | — |
| Reactant | 9-Tetradecenyl formate | HCID 92065 | — |
| Catalyst | HCID 178479819 | HCID 178479819 | — |
| Product | 1-Hexene | HCID 11597 | — |
| Product | Tetradec-9-en-1-ol | HCID 37064 | — |
Reaction Steps
FIG. 9 shows a synthesis of 9-tetradecenyl formate, in which 5-decene is cross-metathesized with 9-decenol in the presence of Grubbs' catalyst to produce 9-tetradecenol while 1-hexene is removed from the reaction under vacuum, and in which the metathesis product, 9-tetradecenol, is reacted with formyl acetate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06215019B1 |
| Source dataset | uspto-grants-2001_04 |
| ORD ID | ord-615d473a08ae41e085a0065bbcfdf238 |
| Source note | uspto-grants-2001_04 |