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Benzyl 4-n-dodecylcarbonyloxybenzoate → 4-n-Dodecylcarbonyloxybenzoic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzyl 4-n-dodecylcarbonyloxybenzoate | HCID 22002898 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Ethyl Acetate | HCID 8857 | — |
| 生成物 | 4-n-Dodecylcarbonyloxybenzoic acid | HCID 22002873 | 87% |
反応手順
{circle around (2)}: A mixture comprising 3.5 g of benzyl 4-n-dodecylcarbonyloxybenzoate, 0.4 g of palladium/carbon and 20 g of ethyl acetate was stirred for 6 hours under hydrogen atmosphere. Then, palladium/carbon was filtered off, and ethyl acetate was distilled off from the filtrate. The resultant residue was recrystallized from toluene, whereby 2.40 g of 4-n-dodecylcarbonyloxybenzoic acid was obtained in the form of a colorless crystal.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06217793B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-6d4cec3c86ba4e7e8177b7e1ef0d4e52 |
| 出典メモ | uspto-grants-2001_04 |