3,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate → 3,7-Dimethyl-6-octenyl 2-oxopentanoate

HRID 324896Notes

Reaction equation

HRID 324896 reaction equation
CC(CCC=C(C)C)CCC(C)C(=O)C([O-])=O.CC(CCC=C(C)C)CCCC(=O)C([O-])=O.C[CH:35]([CH2:51][CH3:52])[C:36](=[O:50])[C:37]([O:39][CH2:40][CH2:41][CH:42]([CH3:49])[CH2:43][CH2:44][CH:45]=[C:46]([CH3:48])[CH3:47])=[O:38]>>[O:50]=[C:36]([CH2:35][CH2:51][CH3:52])[C:37]([O:39][CH2:40][CH2:41][CH:42]([CH3:49])[CH2:43][CH2:44][CH:45]=[C:46]([CH3:47])[CH3:48])=[O:38]

Participants

4

Reactant 3

HCID 129651843,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoateHCID 865836323,7-Dimethyl-6octenyl-2-oxopropanoate3×HCID 865836333,7-Dimethyl-6octenyl-2-oxobutanoate

Product 1

HCID 129651833,7-Dimethyl-6-octenyl 2-oxopentanoate

Procedure

MS (EI): 254 (M+, 1); 236 (2); 226 (1); 193 (1); 183 (6); 165 (1); 155 (7); 138 (15); 137 (10); 123 (26); 118 (3); 109 (17); 95 (41); 83 (15); 82 (32); 81 (54); 71 (87); 69 (100); 67 (23); 55 (34); 43 (66); 41 (72); 27 (14).

Sources & evidence

ORD record
ord-617e7fd10d5141a98468839325deec4c
Source dataset
uspto-grants-2001_04
Patent number
US06218355B1

Reaction notes

Loading…