3,7-Dimethyl-6-octenyl 2-oxopentanoate → 3,7-Dimethyl-6-octenyl (bicyclo[2.2.1]hept-2-yl)oxoacetate

HRID 324905Notes

Reaction equation

HRID 324905 reaction equation
C[CH:2]([CH2:11][CH2:12][CH:13]=C(C)C)[CH2:3][CH2:4][CH2:5][C:6](=[O:10])[C:7]([O-:9])=[O:8].O=C(CCC)C(O[CH2:22][CH2:23][CH:24]([CH3:31])[CH2:25][CH2:26][CH:27]=[C:28]([CH3:30])[CH3:29])=O.CC(CCC=C(C)C)CCC(C)C(=O)C([O-])=O.C1(C(=O)C(OC2CCCC2CCCCC)=O)CCCCC1.CC(CC)C(=O)C(OCCC(C)CCC=C(C)C)=O.O=C(C1C=CC=CC=1)C(OCCC(C)CCC=C(C)C)=O.C1(C(=O)C(OCCCCCCCCCC)=O)CCCCC1.CC(CC)C(=O)C(OC/C=C(\C)/CCC=C(C)C)=O.C(C1C=CC(C(=O)C(OCCC(C)CCC=C(C)C)=O)=CC=1)(=O)C>>[CH:11]12[CH2:2][CH:3]([CH2:13][CH2:12]1)[CH2:4][CH:5]2[C:6](=[O:10])[C:7]([O:9][CH2:22][CH2:23][CH:24]([CH3:31])[CH2:25][CH2:26][CH:27]=[C:28]([CH3:30])[CH3:29])=[O:8]

Participants

10

Reactant 9

HCID 129651833,7-Dimethyl-6-octenyl 2-oxopentanoate4×HCID 129651843,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate7×HCID 12965185(E)-3,7-Dimethyl-2,6-octadienyl 3-methyl-2-oxopentanoateHCID 129781333,7-Dimethyl-6-octenyl oxo(phenyl)acetate6×HCID 129781343,7-Dimethyl-6-octenyl (4-acetylphenyl)oxoacetateHCID 183366652-Pentyl-1-cyclopentyl (cyclohexyl)oxoacetate2×HCID 18336672Decyl (cyclohexyl)oxoacetateHCID 865836323,7-Dimethyl-6octenyl-2-oxopropanoate8×HCID 865836333,7-Dimethyl-6octenyl-2-oxobutanoate6×

Product 1

HCID 183366673,7-Dimethyl-6-octenyl (bicyclo[2.2.1]hept-2-yl)oxoacetate

Procedure

MS (EI): 288 (1); 183 (4); 168 (1); 155 (1); 139 (2); 138 (15); 137 (2); 124 (3); 123 (30); 122 (2); 121 (1); 110 (1); 109 (5); 97 (1); 96 (11); 95 (100); 93 (4); 91 (1); 83 (4); 82 (19); 81 (21); 80 (5); 79 (3); 77 (2); 70 (2); 69 (23); 68 (5); 67 (22); 66 (3); 65 (3); 57 (3); 56 (3); 55 (15); 54 (2); 53 (5); 43 (4); 42 (3); 41 (33); 39 (6); 29 (5); 28 (1); 27 (5).

Sources & evidence

ORD record
ord-2879e690fce74cb9b799b73136d1760e
Source dataset
uspto-grants-2001_04
Patent number
US06218355B1

Reaction notes

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