Lithium hydroxide, monohydrate → HCID 70229363, compound

Participants

Reaction Steps

The product from Example 1302C (107 mg, 0.17 mmol) was allowed to react with lithium hydroxide monohydrate (8 mg, 0.18 mmol) in a manner similar to that described in Example 608E to afford the title compound. 1H NMR (DMSO-d6, 300 MHz) δ 0.54-0.70 (m, 2H), 0.85-1.10 (m, 6H), 1.30-2.04 (m, 16H), 2.14 (m, 1H), 2.80 (m, 1H), 3.16 (m, 1H), 3.60-3.73 (m, 2H), 6.85-7.26 (m, 6H), 7.43 (d, J=8 Hz, 1H), 7.62-7.68 (m, 2H), 7.75 (m, 1H), 7.93 (d, J=7 Hz, 2H); MS (APCI(−)) m/z: (M−H)− 620; Anal. Calcd for C35H42LiNO5S2.3.20 H2O: C, 61.33; H, 7.12; N, 2.04. Found: C, 61.31; H, 6.63; N, 1.70.

Provenance & Evidence