HCID 88719053, compound → HCID 88718787, compound

HRID 325660Notes

Reaction equation

HRID 325660 reaction equation
[Cl:1][CH2:2][C@@H:3]([OH:12])[C@@H:4]([OH:11])[C@@H:5]([OH:10])[C@@H:6]([OH:9])[CH:7]=[O:8]>CO>[Cl:1][CH2:2][C@@H:3]([OH:12])[C@@H:4]([OH:11])[C@@H:5]([OH:10])[C@@H:6]([OH:9])[CH2:7][OH:8]

Participants

3

Reactant 1

HCID 88719053HCID 88719053, compound

Product 1

HCID 88718787HCID 88718787, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

6-Chloro-6-deoxy-D-allose was reduced by the method described in Example 1 to give 6-chloro-6-deoxy-D-allitol as a colourless syrup, [α]D20 +5.3° (c=1.0, methanol); Rf 0.72 (t.l.c. silica gel; n-butanol:ethanol:water, 5:3:2).

Sources & evidence

ORD record
ord-16af23735c9e47e794a8a629a1412bc2
Source dataset
uspto-grants-1984_04
Patent number
US04442123

Reaction notes

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