HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl azide → ethyl 1-benzyl-1H-tetrazole-5-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl azide | HCID 12152 | — |
| Reactant | Ethyl cyanoformate | HCID 69336 | — |
| Solvent | O-Xylene | HCID 7237 | — |
| Product | ethyl 1-benzyl-1H-tetrazole-5-carboxylate | HCID 12752368 | 93.9% |
Reaction Steps
A mixture of freshly prepared benzyl azide (1.3 g) and ethyl cyanoformate (1.0 g) in xylene (10 ml) was heated at reflux for 48 hours. The mixture was evaporated under reduced pressure and below 40° C. to give a residue of ethyl 1-benzyl-1H-tetrazole-5-carboxylate (2.13 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04442115 |
| Source dataset | uspto-grants-1984_04 |
| ORD ID | ord-471225cacb9649ef93dc189a337bd6f4 |
| Source note | uspto-grants-1984_04 |