HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromooctane → 1-n-Octylazacyclononan-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromooctane | HCID 8140 | — |
| Reactant | Octahydro-2H-azonin-2-one | HCID 13632 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Product | 1-n-Octylazacyclononan-2-one | HCID 12833266 | 70% |
Reaction Steps
Following example 17, 4.2 g of 50% sodium hydride-mineral oil dispersion (2.1 g NaH, 0.0875 M), 10 g (0.0708 M) of azacyclononan-2-one and 15 g (0.0777 M) of 1-bromooctane gave 12.5 g (70%) of product; b.p. 150°-160°/0.5 mm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04444762 |
| Source dataset | uspto-grants-1984_04 |
| ORD ID | ord-d69b35b6ef3f46b5be418a26b3725173 |
| Source note | uspto-grants-1984_04 |