HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenyl Trifluoromethanesulfonate → 2-Triethylsilyl-5-phenyl-4-furaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenyl Trifluoromethanesulfonate | HCID 548641 | — |
| Reactant | 3-Furancarboxaldehyde, 5-(triethylsilyl)- | HCID 10878438 | — |
| Reactant | HCID 178506926 | HCID 178506926 | — |
| Catalyst | Zincchloride | HCID 3007855 | — |
| Catalyst | Tetrakis(triphenylphosphine)palladium | HCID 11979704 | — |
| Product | 2-Triethylsilyl-5-phenyl-4-furaldehyde | HCID 19433144 | — |
Reaction Steps
Treatment of 2-triethylsilyl-4-furaldehyde with lithio N,N,N'-trimethylethylenediamine, followed by phenyl trifluoromethanesulfonate in the presence of anhydrous zinc chloride and tetrakis (triphenylphosphine) palladium (O) provides the titled aldehyde.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05268387 |
| Source dataset | uspto-grants-1993_12 |
| ORD ID | ord-4033900a3030452cba0b5a58789e3a38 |
| Source note | uspto-grants-1993_12 |