HRID326678

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID239

beta-Alanine

C3H7NO2

结构：COCCOCOc1c(C(C)(C)C)nc(C=O)nc1C(C)(C)C

HCID19922992

未命名化合物

$结构：COc1ccc(/C=C2\SC(=N)NC2=O)cc1OC1CCCC1$

HCID137629131

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)c1nc(C=C2SC(=N)NC2=O)nc(C(C)(C)C)c1O

HCID140369228

未命名化合物

收率 11.2%

PROCEDURE

实验过程

4,6-Bis-(1,1-dimethylethyl)-5-[(2-methoxyethoxy)methoxy]-2-pyrimidine carboxaldehyde (0.5 g, 1.5 mmoles) is treated with β-alanine (0.27 g, 3.1 mmoles) and pseudothiohydantoin (0.21 g, 1.8 mmoles) according to the procedure of Example 6 to give 0.056 g (11%) of 5-[[4,6-bis-(1,1-dimethylethyl]-5-hydroxy pyrimidinyl]methylene]-2-imino-4-thiazolidinone. MP=278°-281° C. dec.