HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → 1,1'-Biphenyl, 4'-(bromomethyl)-2-nitro-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 4'-Methyl-2-nitro-1,1'-biphenyl | HCID 10443194 | — |
| Catalyst | Azobisisobutyronitrile | HCID 6547 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 1,1'-Biphenyl, 4'-(bromomethyl)-2-nitro- | HCID 11779072 | 101.2% |
Reaction Conditions
| Temperature | 0 °C |
|---|
Reaction Steps
A mixture containing 6.5 g of 4-methyl-2'-nitrobiphenyl, 5.42 g of NBS, 118 mg of azo-bis-isobutyronitrile and 500 ml of carbon tetrachloride is refluxed for 5 hours. It is cooled to 0° C. and filtered and the filtrate is concentrated to give 9 g of an oily product, which is used as such in the next step.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05270317 |
| Source dataset | uspto-grants-1993_12 |
| ORD ID | ord-24278e22323e4ebf969f711e19fec804 |
| Source note | uspto-grants-1993_12 |