Benzyl Alcohol → benzyl N-(chlorosulfonyl)carbamate

HRID 327681Notes

Reaction equation

[CH2:1]([OH:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:9][S:10]([N:13]=[C:14]=[O:15])(=[O:12])=[O:11]>>[CH2:1]([O:8][C:14]([NH:13][S:10]([Cl:9])(=[O:12])=[O:11])=[O:15])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 244Benzyl Alcohol

HCID 70918Chlorosulfonyl isocyanate

Product 1

HCID 14947136benzyl N-(chlorosulfonyl)carbamate

Procedure

The procedure of Example 7 was followed scaling the reaction to 0.2 moles each of benzyl alcohol and chlorosulfonyl isocyanate to give benzyloxycarbonylsulfamoyl chloride.

Sources & evidence

ORD record: ord-eaecab5b19e847d4b0cdb147accc6ff1
Source dataset: uspto-grants-1993_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05273993

Reaction notes

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